SUMMARY OF PM7 CALCULATION, Site No: 23746 MOPAC2016 (Version: 21.055M) Thu Feb 25 17:41:31 2021 No. of days remaining = 364 Empirical Formula: C10 H14 O4 Os Br2 = 31 atoms MERS=(1,1,1) CHARGE=0 OUTPUT THREADS=1 PM7 GRADIENTS NOTXT EF trans-bis(Acetylacetonato)-dibromo-osmium (RILRUZ) GRADIENTS WERE INITIALLY ACCEPTABLY SMALL SCF FIELD WAS ACHIEVED HEAT OF FORMATION = -223.46725 KCAL/MOL = -934.98699 KJ/MOL H.o.F. per unit cell = -223.46725 KCAL, for 1 unit cells, unit cell = C10 H14 O4 OsBr2 TOTAL ENERGY = -3425.58212 EV ELECTRONIC ENERGY = -9189268.33598 EV CORE-CORE REPULSION = 9185842.75386 EV VOLUME OF UNIT CELL = 396.689 CUBIC ANGSTROMS DENSITY = 2.295 GRAMS/CC A = 9.163 ANGSTROMS B = 7.713 ANGSTROMS C = 7.473 ANGSTROMS ALPHA = 117.093 DEGREES BETA = 87.387 DEGREES GAMMA = 119.793 DEGREES GRADIENT NORM = 4.48862 = 0.80618 PER ATOM NO. OF FILLED LEVELS = 50 IONIZATION POTENTIAL = 9.226909 EV HOMO LUMO ENERGIES (EV) = -9.227 -1.252 MOLECULAR WEIGHT = 548.2262 Pressure required to constrain translation vectors Tv( 32) Pressure: -0.04 GPa Tv( 33) Pressure: -0.22 GPa Tv( 34) Pressure: 0.12 GPa SCF CALCULATIONS = 1 WALL-CLOCK TIME = 6.047 SECONDS COMPUTATION TIME = 5.923 SECONDS FINAL GEOMETRY OBTAINED MERS=(1,1,1) CHARGE=0 OUTPUT THREADS=1 PM7 GRADIENTS NOTXT EF trans-bis(Acetylacetonato)-dibromo-osmium (RILRUZ) Os -0.02293629 +1 -0.00630759 +1 0.01117376 +1 Br 2.48692331 +1 -0.28778490 +1 0.58399932 +1 O 0.29288419 +1 1.90166565 +1 -0.15751314 +1 O 0.43435365 +1 0.11615454 +1 -1.87629370 +1 C -0.31214160 +1 4.11722339 +1 -0.61141571 +1 H -1.34725367 +1 4.45595244 +1 -0.81042882 +1 H 0.34648310 +1 4.85390362 +1 -1.10577554 +1 H -0.14021615 +1 4.23255555 +1 0.47623347 +1 C -0.08292743 +1 2.73996524 +1 -1.08548468 +1 C -0.16360480 +1 2.31316569 +1 -2.41108674 +1 H -0.39141630 +1 3.04508959 +1 -3.19007832 +1 C 0.05695854 +1 0.98355256 +1 -2.77408806 +1 C -0.03016357 +1 0.45346550 +1 -4.14815501 +1 H 0.43969005 +1 1.11056460 +1 -4.89822256 +1 H -1.08580949 +1 0.32773262 +1 -4.46263449 +1 H 0.43624094 +1 -0.54500886 +1 -4.25737173 +1 Br -2.53382010 +1 0.27916779 +1 -0.56078080 +1 O -0.33433675 +1 -1.91589166 +1 0.17809035 +1 C 0.05026150 +1 -2.75357287 +1 1.10236821 +1 C 0.29786008 +1 -4.12632828 +1 0.62570615 +1 H 1.33542032 +1 -4.45304074 +1 0.83233627 +1 H -0.35466608 +1 -4.87168499 +1 1.11488798 +1 H 0.13532068 +1 -4.24262456 +1 -0.46337823 +1 C 0.12864515 +1 -2.32900365 +1 2.42988377 +1 H 0.35920147 +1 -3.06113017 +1 3.20818156 +1 C -0.09170843 +1 -0.99956809 +1 2.79206787 +1 O -0.47968161 +1 -0.13322237 +1 1.89713368 +1 C 0.01502242 +1 -0.46569062 +1 4.16297339 +1 H -0.43873899 +1 -1.12175837 +1 4.92320681 +1 H 1.07632519 +1 -0.33573778 +1 4.45737046 +1 H -0.45334303 +1 0.53148230 +1 4.27595801 +1 Tv -8.79376262 +1 2.02373356 +1 1.59147934 +1 Tv 2.20662802 +1 -2.21920254 +1 -7.04938325 +1 Tv 1.62420023 +1 7.00676808 +1 2.02620423 +1